Enhancing both functionality and performance, synergy between disparate materials precisely localized in a hierarchical structure is ubiquitous in nature. This level of sophistication in materials provides unparalleled properties that could lead to advanced technologies in a variety of sectors, from medical and environmental to communication and transportation. However, scalable access to such structures remains elusive. This sub-group aims to create bioinspired hierarchical multi-material polymer networks with unique compositions and properties by developing and combining orthogonal chemical reactions. Research consists of reaction screening, morphological characterization, and thermomechanical testing of patterned multi-material structures.